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Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent

Received: 4 May 2021     Accepted: 21 May 2021     Published: 27 May 2021
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Abstract

This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.

Published in American Journal of Chemical and Biochemical Engineering (Volume 5, Issue 1)
DOI 10.11648/j.ajcbe.20210501.14
Page(s) 26-31
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Arsenic, Fenugreek, Biosorption, Isotherms, Kinetic Order, Thermodynamics

References
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[8] Mohammed A. H. Dhaif-Allah, Syed Noeman Taqui, Usman Taqui Syed, Akheel Ahmed Syed. (2020). “Kinetic and isotherm modeling for acidblue113 dye adsorption onto low-cost nutraceutical industrial fenugreek seed spent” Applied Water Science 10: 58 https://doi.org/10.1007/s13201-020-1141-3.
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[13] Maedeh Mohammadi, Ali J. Hassani, Abdul Rahman Mohamed and Ghasem D. Najafpur, (2010), Removal of Rhodamine B from aqueous solution using palm shell based activated carbon: Adsorption and kinetic studies. Journal of Chemical and Engineering Data. 55: 5777–5785.
[14] Sharma, Y. C, (2011), Adsorption characteristics of a low-cost activated carbon for the reclamation of coloured effluents containing malachite Green. Journal of Chemical and Engineering Data. 56: 478–484.
[15] Ravindra Kumar Gautam, Ackmez Mudhoo, Mahesh Chandra Chattopadhya, (2013), Kinetic, equilibrium, thermodynamic studies and spectroscopic analysis of Alizarin Red S by removal by mustard husk. Journal of environmental Chemical Engineering. 1: 1283-1291.
[16] Eftekhari, S. Habibi–Yangjeh, A., Sohrabnezhad. S., (2010), Application of AIMCM-41 for competitive adsorption of methylene blue and rhodamine B: Thermodynmic and Kinetic studies. Journal of Hazardous Materials. 178 (1-3): 349-355.
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    Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David. (2021). Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. American Journal of Chemical and Biochemical Engineering, 5(1), 26-31. https://doi.org/10.11648/j.ajcbe.20210501.14

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    ACS Style

    Vijayarani Allam; Sailaja Budati Bala Venkata; Sirisha David. Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. Am. J. Chem. Biochem. Eng. 2021, 5(1), 26-31. doi: 10.11648/j.ajcbe.20210501.14

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    AMA Style

    Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David. Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. Am J Chem Biochem Eng. 2021;5(1):26-31. doi: 10.11648/j.ajcbe.20210501.14

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  • @article{10.11648/j.ajcbe.20210501.14,
      author = {Vijayarani Allam and Sailaja Budati Bala Venkata and Sirisha David},
      title = {Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent},
      journal = {American Journal of Chemical and Biochemical Engineering},
      volume = {5},
      number = {1},
      pages = {26-31},
      doi = {10.11648/j.ajcbe.20210501.14},
      url = {https://doi.org/10.11648/j.ajcbe.20210501.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajcbe.20210501.14},
      abstract = {This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent
    AU  - Vijayarani Allam
    AU  - Sailaja Budati Bala Venkata
    AU  - Sirisha David
    Y1  - 2021/05/27
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajcbe.20210501.14
    DO  - 10.11648/j.ajcbe.20210501.14
    T2  - American Journal of Chemical and Biochemical Engineering
    JF  - American Journal of Chemical and Biochemical Engineering
    JO  - American Journal of Chemical and Biochemical Engineering
    SP  - 26
    EP  - 31
    PB  - Science Publishing Group
    SN  - 2639-9989
    UR  - https://doi.org/10.11648/j.ajcbe.20210501.14
    AB  - This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.
    VL  - 5
    IS  - 1
    ER  - 

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Author Information
  • Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam, India

  • Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam, India

  • Department of Chemistry, St. Ann’s Degree College for Women, Osmania University, Hyderabad, India

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